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Formation of Ruthenium Carbenes by gem‐Hydrogen Transfer to Internal Alkynes: Implications for Alkyne trans‐Hydrogenation

Insights into the mechanism of the unusual trans‐hydrogenation of internal alkynes catalyzed by {Cp*Ru} complexes were gained by para‐hydrogen (p‐H(2)) induced polarization (PHIP) transfer NMR spectroscopy. It was found that the productive trans‐reduction competes with a pathway in which both H atom...

詳細記述

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書誌詳細
出版年:Angew Chem Weinheim Bergstr Ger
主要な著者: Leutzsch, Markus, Wolf, Larry M., Gupta, Puneet, Fuchs, Michael, Thiel, Walter, Farès, Christophe, Fürstner, Alois
フォーマット: Artigo
言語:Inglês
出版事項: WILEY‐VCH Verlag 2015
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC4955229/
https://ncbi.nlm.nih.gov/pubmed/27478268
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ange.201506075
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