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Ruthenium-Catalyzed trans-Hydroalkynylation and trans-Chloroalkynylation of Internal Alkynes
[Image: see text] [Cp*RuCl](4) catalyzes the addition of iPr(3)SiC≡CX (X = H, Cl) across internal alkynes with formation of 1,3-enyne or 1-chloro-1,3-enyne derivatives, respectively; the reaction follows an unorthodox trans-addition mode. The well-balanced affinities of the different reaction partne...
में बचाया:
| में प्रकाशित: | J Am Chem Soc |
|---|---|
| मुख्य लेखकों: | , , |
| स्वरूप: | Artigo |
| भाषा: | Inglês |
| प्रकाशित: |
American Chemical
Society
2020
|
| ऑनलाइन पहुंच: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7660751/ https://ncbi.nlm.nih.gov/pubmed/33095568 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c08582 |
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