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Hydrogenative Metathesis of Enynes via Piano-Stool Ruthenium Carbene Complexes Formed by Alkyne gem-Hydrogenation

[Image: see text] The only recently discovered gem-hydrogenation of internal alkynes is a fundamentally new transformation, in which both H atoms of dihydrogen are transferred to the same C atom of a triple bond while the other position transforms into a discrete metal carbene complex. [Cp*RuCl](4)...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Peil, Sebastian, Bistoni, Giovanni, Goddard, Richard, Fürstner, Alois
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2020
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7596760/
https://ncbi.nlm.nih.gov/pubmed/33073575
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c07808
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