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Hydrogenative Metathesis of Enynes via Piano-Stool Ruthenium Carbene Complexes Formed by Alkyne gem-Hydrogenation
[Image: see text] The only recently discovered gem-hydrogenation of internal alkynes is a fundamentally new transformation, in which both H atoms of dihydrogen are transferred to the same C atom of a triple bond while the other position transforms into a discrete metal carbene complex. [Cp*RuCl](4)...
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| Published in: | J Am Chem Soc |
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| Main Authors: | , , , |
| Format: | Artigo |
| Language: | Inglês |
| Published: |
American Chemical
Society
2020
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| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7596760/ https://ncbi.nlm.nih.gov/pubmed/33073575 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c07808 |
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