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Sequence sensitivity and pH dependence of maleimide conjugated N‐terminal cysteine peptides to thiazine rearrangement

Thiazine formation during the conjugation of N‐terminal cysteine peptides to maleimides is an underreported side reaction in the peptide literature. When the conjugation was performed at neutral and basic pH, we observed the thiazine isomer as a significant by‐product. Nuclear magnetic resonance (NM...

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Detalhes bibliográficos
Publicado no:J Pept Sci
Main Authors: Gober, Isaiah N., Riemen, Alexander J., Villain, Matteo
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2021
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8243948/
https://ncbi.nlm.nih.gov/pubmed/33786923
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/psc.3323
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