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Hydrogen-bond-induced selectivity of a head-to-head photo-dimerisation of dialkynylanthracene – access to tetradentate Lewis acids
Using 2-hydroxypropyl-protecting groups, 1,8-dialkynylanthracene photo-dimers were prepared in head-to-head-configuration by UV irradiation on a multi-gram scale. In non-polar solvents, the combination of non-covalent hydrogen bonds and π–π-interactions induces the formation of the syn-isomer in up...
Gorde:
| Argitaratua izan da: | Chem Sci |
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| Egile Nagusiak: | , , , , , |
| Formatua: | Artigo |
| Hizkuntza: | Inglês |
| Argitaratua: |
The Royal Society of Chemistry
2021
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| Gaiak: | |
| Sarrera elektronikoa: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8230024/ https://ncbi.nlm.nih.gov/pubmed/34257857 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d1sc02065j |
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