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Regiochemical Control in Triptycene Formation—An Exercise in Subtle Balancing Multiple Factors
Reactions between 1,8‐dichloroanthracenes with substituents in position 10 and ortho‐chloroaryne afford mixtures of 1,8,13‐ (syn) and 1,8,16‐trichlorotriptycenes (anti). The syn/anti ratio is dependent on these substituents. Electropositive substituents like SiMe(3) and GeMe(3) lead to preferred for...
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| Publicado no: | ChemistryOpen |
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| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
John Wiley and Sons Inc.
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5765815/ https://ncbi.nlm.nih.gov/pubmed/29344439 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/open.201700196 |
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