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Electrochemical studies of tris(cyclopentadienyl)thorium and uranium complexes in the +2, +3, and +4 oxidation states

Electrochemical measurements on tris(cyclopentadienyl)thorium and uranium compounds in the +2, +3, and +4 oxidation states are reported with C(5)H(3)(SiMe(3))(2), C(5)H(4)SiMe(3), and C(5)Me(4)H ligands. The reduction potentials for both U and Th complexes trend with the electron donating abilities...

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Publicado en:Chem Sci
Main Authors: Wedal, Justin C., Barlow, Jeffrey M., Ziller, Joseph W., Yang, Jenny Y., Evans, William J.
Formato: Artigo
Idioma:Inglês
Publicado: The Royal Society of Chemistry 2021
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC8221189/
https://ncbi.nlm.nih.gov/pubmed/34221331
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d1sc01906f
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