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Intramolecular hydrogen-bonding in a cobalt aqua complex and electrochemical water oxidation activity
Water oxidation is catalysed in Nature by a redox cofactor embedded in a hydrogen-bonded network designed to orchestrate proton transfer throughout the challenging 4 electron reaction. In order to mimic aspects of this microenvironment, [CoL(DMA)(CH(3)CN)(2)][BF(4)](2) (2) was synthesized, where L(D...
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| Publicado no: | Chem Sci |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5912104/ https://ncbi.nlm.nih.gov/pubmed/29732059 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc04960a |
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