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“Anti-electrostatic” halogen bonding in solution

Halogen-bonded (XB) complexes between halide anions and a cyclopropenylium-based anionic XB donor were characterized in solution for the first time. Spontaneous formation of such complexes confirms that halogen bonding is sufficiently strong to overcome electrostatic repulsion between two anions. Th...

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書目詳細資料
發表在:Chem Sci
Main Authors: Loy, Cody, Holthoff, Jana M., Weiss, Robert, Huber, Stefan M., Rosokha, Sergiy V.
格式: Artigo
語言:Inglês
出版: The Royal Society of Chemistry 2021
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在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC8208320/
https://ncbi.nlm.nih.gov/pubmed/34194716
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d1sc01863a
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