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“Anti-electrostatic” halogen bonding in solution

Halogen-bonded (XB) complexes between halide anions and a cyclopropenylium-based anionic XB donor were characterized in solution for the first time. Spontaneous formation of such complexes confirms that halogen bonding is sufficiently strong to overcome electrostatic repulsion between two anions. Th...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Loy, Cody, Holthoff, Jana M., Weiss, Robert, Huber, Stefan M., Rosokha, Sergiy V.
Formato: Artigo
Idioma:Inglês
Publicado em: The Royal Society of Chemistry 2021
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8208320/
https://ncbi.nlm.nih.gov/pubmed/34194716
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d1sc01863a
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