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“Anti-electrostatic” halogen bonding in solution

Halogen-bonded (XB) complexes between halide anions and a cyclopropenylium-based anionic XB donor were characterized in solution for the first time. Spontaneous formation of such complexes confirms that halogen bonding is sufficiently strong to overcome electrostatic repulsion between two anions. Th...

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Bibliographic Details
Published in:Chem Sci
Main Authors: Loy, Cody, Holthoff, Jana M., Weiss, Robert, Huber, Stefan M., Rosokha, Sergiy V.
Format: Artigo
Language:Inglês
Published: The Royal Society of Chemistry 2021
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Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC8208320/
https://ncbi.nlm.nih.gov/pubmed/34194716
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d1sc01863a
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