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Transition-metal-like bonding behaviors of a boron atom in a boron-cluster boronyl complex [(η(7)-B(7))-B-BO](−)

Boron displays many unusual structural and bonding properties due to its electron deficiency. Here we show that a boron atom in a boron monoxide cluster (B(9)O(−)) exhibits transition-metal-like properties. Temperature-dependent photoelectron spectroscopy provided evidence of the existence of two is...

Täydet tiedot

Tallennettuna:
Bibliografiset tiedot
Julkaisussa:Chem Sci
Päätekijät: Tian, Wen-Juan, Chen, Wei-Jia, Yan, Miao, Li, Rui, Wei, Zhi-Hong, Chen, Teng-Teng, Chen, Qiang, Zhai, Hua-Jin, Li, Si-Dian, Wang, Lai-Sheng
Aineistotyyppi: Artigo
Kieli:Inglês
Julkaistu: The Royal Society of Chemistry 2021
Aiheet:
Linkit:https://ncbi.nlm.nih.gov/pmc/articles/PMC8208299/
https://ncbi.nlm.nih.gov/pubmed/34194706
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d1sc00534k
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