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Double C–H bond activation of acetylene by atomic boron in forming aromatic cyclic-HBC(2)BH in solid neon
The organo-boron species formed from the reactions of boron atoms with acetylene in solid neon are investigated using matrix isolation infrared spectroscopy with isotopic substitutions as well as quantum chemical calculations. Besides the previously reported single C–H bond activation species, a cyc...
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| Publicado no: | Chem Sci |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5590098/ https://ncbi.nlm.nih.gov/pubmed/28936331 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc01399j |
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