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Transition-metal-like bonding behaviors of a boron atom in a boron-cluster boronyl complex [(η(7)-B(7))-B-BO](−)
Boron displays many unusual structural and bonding properties due to its electron deficiency. Here we show that a boron atom in a boron monoxide cluster (B(9)O(−)) exhibits transition-metal-like properties. Temperature-dependent photoelectron spectroscopy provided evidence of the existence of two is...
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| Udgivet i: | Chem Sci |
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| Main Authors: | , , , , , , , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
The Royal Society of Chemistry
2021
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8208299/ https://ncbi.nlm.nih.gov/pubmed/34194706 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d1sc00534k |
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