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Overcoming Kinetic and Thermodynamic Challenges of Classic Cope Rearrangements
Systematic evaluation of 1,5-dienes bearing 3,3-electron-withdrawing groups and 4-methylation results in the discovery of a Cope rearrangement for Meldrum’s acid-containing substrates that have unexpectedly favorable kinetic and thermodynamic profiles. The protocol is quite general due to a concise...
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| Publicado no: | J Org Chem |
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| Main Authors: | , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2021
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8195263/ https://ncbi.nlm.nih.gov/pubmed/33476142 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.0c02690 |
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