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Oxidative additions of alkynyl/vinyl iodides to gold and gold-catalyzed vinylation reactions triggered by the MeDalphos ligand

The hemilabile Ad(2)P(o-C(6)H(4))NMe(2) ligand promotes fast, quantitative and irreversible oxidative addition of alkynyl and vinyl iodides to gold. The reaction is general. It works with a broad range of substrates of various electronic bias and steric demand, and proceeds with complete retention o...

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Shranjeno v:
Bibliografske podrobnosti
izdano v:Chem Sci
Main Authors: Rodriguez, Jessica, Tabey, Alexis, Mallet-Ladeira, Sonia, Bourissou, Didier
Format: Artigo
Jezik:Inglês
Izdano: The Royal Society of Chemistry 2021
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC8188461/
https://ncbi.nlm.nih.gov/pubmed/34168822
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d1sc01483h
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