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Gold(iii)–arene complexes by insertion of olefins into gold–aryl bonds

The synthesis and characterization of the first gold(iii)–arene complexes are described. Well-defined (P,C)-cyclometalated gold(iii)–aryl complexes were prepared and characterized by NMR spectroscopy. These complexes swiftly and cleanly reacted with norbornene and ethylene to provide cationic gold(i...

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Publicat a:Chem Sci
Autors principals: Rekhroukh, Feriel, Blons, Charlie, Estévez, Laura, Mallet-Ladeira, Sonia, Miqueu, Karinne, Amgoune, Abderrahmane, Bourissou, Didier
Format: Artigo
Idioma:Inglês
Publicat: Royal Society of Chemistry 2017
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5472032/
https://ncbi.nlm.nih.gov/pubmed/28660067
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc00145b
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