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Rearrangement of Biaryl Monoaminocarbenes via Concerted Asynchronous Insertion into Aromatic C — H Bonds
[Image: see text] The biphenyl and binaphthyl diisopropylaminocarbenes were found to be only transient species that spontaneously and quantitatively rearrange into the corresponding aminofluorenes. DFT calculations confirm that these insertion reactions of aminocarbenes into proximal aromatic C—H bo...
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| Main Authors: | , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2008
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2601701/ https://ncbi.nlm.nih.gov/pubmed/18763790 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol801670z |
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