Catalytic Au(i)/Au(iii) arylation with the hemilabile MeDalphos ligand: unusual selectivity for electron-rich iodoarenes and efficient application to indoles

The ability of the hemilabile (P,N) MeDalphos ligand to trigger oxidative addition of iodoarenes to gold has been thoroughly studied. Competition experiments and Hammett correlations substantiate a clear preference of gold for electron-enriched substrates both in stoichiometric oxidative addition re...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Rodriguez, Jessica, Zeineddine, Abdallah, Sosa Carrizo, E. Daiann, Miqueu, Karinne, Saffon-Merceron, Nathalie, Amgoune, Abderrahmane, Bourissou, Didier
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2019
Assuntos:
Chemistry
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6685352/
https://ncbi.nlm.nih.gov/pubmed/31588286
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc01954e
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