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Masked Radicals: Iron Complexes of Trityl, Benzophenone, and Phenylacetylene
We report the first Fe─CPh(3) complex, and show that the long Fe─C bond can be disrupted by neutral π-acceptor ligands (benzophenone and phenylacetylene) to release the triphenylmethyl radical. The products are formally iron(I) complexes, but X-ray absorption spectroscopy coupled with density functi...
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| Publicado no: | Organometallics |
|---|---|
| Main Authors: | , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8184022/ https://ncbi.nlm.nih.gov/pubmed/34103782 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.organomet.9b00534 |
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