Formation of Hexacoordinate Mn(III) in Bacillus subtilis Oxalate Decarboxylase Requires Catalytic Turnover

Oxalate decarboxylase (OxDC) catalyzes the disproportionation of oxalic acid monoanion into CO(2) and formate. The enzyme has long been hypothesized to utilize dioxygen to form mononuclear Mn(III) or Mn(IV) in the catalytic site during turnover. Recombinant OxDC, however, contains only tightly bound...

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Bibliographic Details
Published in:Biochemistry
Main Authors: Zhu, Wen, Wilcoxen, Jarett, Britt, R. David, Richards, Nigel G. J.
Format: Artigo
Language:Inglês
Published: 2016
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Article
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC8183094/
https://ncbi.nlm.nih.gov/pubmed/26744902
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.biochem.5b01340
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