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Formation of Hexacoordinate Mn(III) in Bacillus subtilis Oxalate Decarboxylase Requires Catalytic Turnover
Oxalate decarboxylase (OxDC) catalyzes the disproportionation of oxalic acid monoanion into CO(2) and formate. The enzyme has long been hypothesized to utilize dioxygen to form mononuclear Mn(III) or Mn(IV) in the catalytic site during turnover. Recombinant OxDC, however, contains only tightly bound...
Tallennettuna:
| Julkaisussa: | Biochemistry |
|---|---|
| Päätekijät: | , , , |
| Aineistotyyppi: | Artigo |
| Kieli: | Inglês |
| Julkaistu: |
2016
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| Aiheet: | |
| Linkit: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8183094/ https://ncbi.nlm.nih.gov/pubmed/26744902 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.biochem.5b01340 |
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