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Asymmetric total synthesis of (+)-xestoquinone and (+)-adociaquinones A and B

The asymmetric total synthesis of (+)-xestoquinone and (+)-adociaquinones A and B was achieved in 6–7 steps using an easily accessible meso-cyclohexadienone derivative. The [6,6]-bicyclic decalin B–C ring and the all-carbon quaternary stereocenter at C-6 were prepared via a desymmetric intramolecula...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Lu, Xiao-Long, Qiu, Yuanyou, Yang, Baochao, He, Haibing, Gao, Shuanhu
Formato: Artigo
Idioma:Inglês
Publicado em: The Royal Society of Chemistry 2021
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8179641/
https://ncbi.nlm.nih.gov/pubmed/34168753
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc07089k
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