Synthesis of an elusive, stable 2-azaallyl radical guided by electrochemical and reactivity studies of 2-azaallyl anions

The super electron donor (SED) ability of 2-azaallyl anions has recently been discovered and applied to diverse reactivity, including transition metal-free cross-coupling and dehydrogenative cross-coupling processes. Surprisingly, the redox properties of 2-azaallyl anions and radicals have been rare...

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Bibliographic Details
Published in:Chem Sci
Main Authors: Panetti, Grace B., Carroll, Patrick J., Gau, Michael R., Manor, Brian C., Schelter, Eric J., Walsh, Patrick J.
Format: Artigo
Language:Inglês
Published: The Royal Society of Chemistry 2021
Subjects:
Chemistry
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC8179533/
https://ncbi.nlm.nih.gov/pubmed/34163704
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc04822d
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