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Tandem diaza-Cope rearrangement polymerization: turning intramolecular reaction into powerful polymerization to give enantiopure materials for Zn(2+) sensors

[3,3]-Sigmatropic rearrangement is a powerful reaction to form C–C bonds stereospecifically; however, owing to intrinsic simultaneous bond formation and breakage, this versatile method has not been utilized in polymerization. Herein, we report a new tandem diaza-Cope rearrangement polymerization (DC...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Hwang, Soon-Hyeok, Choi, Tae-Lim
Formato: Artigo
Idioma:Inglês
Publicado em: The Royal Society of Chemistry 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8179250/
https://ncbi.nlm.nih.gov/pubmed/34164005
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc06138g
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