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A Tandem Iridium-Catalyzed “Chain-Walking”/Cope Rearrangement Sequence
[Image: see text] An iridium-catalyzed tandem olefin migration/Cope rearrangement of alkenyl ω-ene cyclopropanes is reported. By this means, a variety of complex annulenes are obtained as single diastereomers starting from cyclopropyl ester derived from simple 1,ω-dienes and alkenyldiazo compounds....
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| Published in: | ACS Catal |
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| Main Authors: | , , |
| Format: | Artigo |
| Language: | Inglês |
| Published: |
American Chemical
Society
2019
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| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7493306/ https://ncbi.nlm.nih.gov/pubmed/32953237 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.9b00118 |
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