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Radical-Polar Crossover Annulation: A Platform for Accessing Polycyclic Cyclopropanes

Photoredox-mediated radical/polar crossover (RPC) processes provide unique solutions to challenging annulations. Herein, we describe an approach to the cyclopropanation of olefins that are embedded within bicyclic scaffolds. Whereas these systems are notoriously recalcitrant toward classical cyclopr...

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Detalhes bibliográficos
Publicado no:Adv Synth Catal
Main Authors: Milligan, John A., Burns, Kevin L., Le, Anthony V., Polites, Viktor C., Wang, Zheng-Jun, Molander, Gary A., Kelly, Christopher B.
Formato: Artigo
Idioma:Inglês
Publicado em: 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8172062/
https://ncbi.nlm.nih.gov/pubmed/34084099
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/adsc.201901051
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