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Radical-Polar Crossover Annulation: A Platform for Accessing Polycyclic Cyclopropanes

Photoredox-mediated radical/polar crossover (RPC) processes provide unique solutions to challenging annulations. Herein, we describe an approach to the cyclopropanation of olefins that are embedded within bicyclic scaffolds. Whereas these systems are notoriously recalcitrant toward classical cyclopr...

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Détails bibliographiques
Publié dans:Adv Synth Catal
Auteurs principaux: Milligan, John A., Burns, Kevin L., Le, Anthony V., Polites, Viktor C., Wang, Zheng-Jun, Molander, Gary A., Kelly, Christopher B.
Format: Artigo
Langue:Inglês
Publié: 2019
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC8172062/
https://ncbi.nlm.nih.gov/pubmed/34084099
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/adsc.201901051
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