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Radical/Polar Annulation Reactions (RPARs) Enable the Modular Construction of Cyclopropanes
An annulation process for the construction of 1,1-disubstituted cyclopropanes via a radical/polar crossover process is described. The cyclopropanation proceeds by the addition of a photocatalytically generated radical to a homoallylic tosylate. Reduction of the intermediate radical alkylation adduct...
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| Udgivet i: | Org Lett |
|---|---|
| Main Authors: | , , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2018
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6218941/ https://ncbi.nlm.nih.gov/pubmed/30350660 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.8b02968 |
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