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Redox-Neutral Photocatalytic Cyclopropanation via Radical/Polar Crossover
A bench-top stable, bifunctional reagent for the redox-neutral cyclopropanation of olefins has been developed. Triethylammonium bis(catecholato)iodomethylsilicate can be readily prepared on multigram scale. Using this reagent in combination with an organic photocatalyst and visible light, cyclopropa...
Gorde:
| Argitaratua izan da: | J Am Chem Soc |
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| Egile Nagusiak: | , , , , , , |
| Formatua: | Artigo |
| Hizkuntza: | Inglês |
| Argitaratua: |
2018
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| Gaiak: | |
| Sarrera elektronikoa: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6540794/ https://ncbi.nlm.nih.gov/pubmed/29916711 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b05243 |
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