Redox-Neutral Photocatalytic Cyclopropanation via Radical/Polar Crossover

A bench-top stable, bifunctional reagent for the redox-neutral cyclopropanation of olefins has been developed. Triethylammonium bis(catecholato)iodomethylsilicate can be readily prepared on multigram scale. Using this reagent in combination with an organic photocatalyst and visible light, cyclopropa...

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Bibliografiske detaljer
Udgivet i:J Am Chem Soc
Main Authors: Phelan, James P., Lang, Simon B., Compton, Jordan S., Kelly, Christopher B., Dykstra, Ryan, Gutierrez, Osvaldo, Molander, Gary A.
Format: Artigo
Sprog:Inglês
Udgivet: 2018
Fag:
Article
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6540794/
https://ncbi.nlm.nih.gov/pubmed/29916711
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b05243
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