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Redox-Neutral Photocatalytic Cyclopropanation via Radical/Polar Crossover
A bench-top stable, bifunctional reagent for the redox-neutral cyclopropanation of olefins has been developed. Triethylammonium bis(catecholato)iodomethylsilicate can be readily prepared on multigram scale. Using this reagent in combination with an organic photocatalyst and visible light, cyclopropa...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6540794/ https://ncbi.nlm.nih.gov/pubmed/29916711 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b05243 |
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