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Exohedral functionalization vs. core expansion of siliconoids with Group 9 metals: catalytic activity in alkene isomerization

Taking advantage of pendant tetrylene side-arms, stable unsaturated Si(6) silicon clusters (siliconoids) with the benzpolarene motif (the energetic counterpart of benzene in silicon chemistry) are successfully employed as ligands towards Group 9 metals. The pronounced σ-donating properties of the te...

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Pubblicato in:Chem Sci
Autori principali: Poitiers, Nadine E., Giarrana, Luisa, Huch, Volker, Zimmer, Michael, Scheschkewitz, David
Natura: Artigo
Lingua:Inglês
Pubblicazione: The Royal Society of Chemistry 2020
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC8163246/
https://ncbi.nlm.nih.gov/pubmed/34094151
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc02861d
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