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Exohedral functionalization vs. core expansion of siliconoids with Group 9 metals: catalytic activity in alkene isomerization
Taking advantage of pendant tetrylene side-arms, stable unsaturated Si(6) silicon clusters (siliconoids) with the benzpolarene motif (the energetic counterpart of benzene in silicon chemistry) are successfully employed as ligands towards Group 9 metals. The pronounced σ-donating properties of the te...
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| Pubblicato in: | Chem Sci |
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| Autori principali: | , , , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
The Royal Society of Chemistry
2020
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8163246/ https://ncbi.nlm.nih.gov/pubmed/34094151 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc02861d |
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