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Chalcogen‐Expanded Unsaturated Silicon Clusters: Thia‐, Selena‐, and Tellurasiliconoids
Reactions of silylenes with heavier chalcogens (E) typically result in Si=E double bonds or their π‐addition products. In contrast, the oxidation of a silylene‐functionalized unsaturated silicon cluster (siliconoid) with Group 16 elements selectively yields cluster expanded siliconoids Si(7)E (E=S,...
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| 發表在: | Chemistry |
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| Main Authors: | , , , |
| 格式: | Artigo |
| 語言: | Inglês |
| 出版: |
John Wiley and Sons Inc.
2020
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| 主題: | |
| 在線閱讀: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7756652/ https://ncbi.nlm.nih.gov/pubmed/32700779 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202003180 |
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