Chiral Fe(ii) complex catalyzed enantioselective [1,3] O-to-C rearrangement of alkyl vinyl ethers and synthesis of chromanols and beyond

A highly efficient enantioselective [1,3] O-to-C rearrangement of racemic vinyl ethers that operates under mild conditions was developed. This method with chiral ferrous complex catalyst provided an efficient access to a wide range of chromanols with high yields and excellent enantioselectivities. I...

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Bibliographic Details
Published in:Chem Sci
Main Authors: Wang, Lifeng, Zhou, Pengfei, Lin, Qianchi, Dong, Shunxi, Liu, Xiaohua, Feng, Xiaoming
Format: Artigo
Language:Inglês
Published: The Royal Society of Chemistry 2020
Subjects:
Chemistry
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC8162448/
https://ncbi.nlm.nih.gov/pubmed/34094271
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc04340k
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