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Chiral N,N′-dioxide/Mg(OTf)(2) complex-catalyzed asymmetric [2,3]-rearrangement of in situ generated ammonium salts
Catalytic enantioselective [2,3]-rearrangements of in situ generated ammonium ylides from glycine pyrazoleamides and allyl bromides were achieved by employing a chiral N,N′-dioxide/Mg(II) complex as the catalyst. This protocol provided a facile and efficient synthesis route to a series of anti-α-ami...
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| Publicado no: | Chem Sci |
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| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
The Royal Society of Chemistry
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8157646/ https://ncbi.nlm.nih.gov/pubmed/34122811 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc06342k |
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