Chemically driven superstructural ordering leading to giant unit cells in unconventional clathrates Cs(8)Zn(18)Sb(28) and Cs(8)Cd(18)Sb(28)

The unconventional clathrates, Cs(8)Zn(18)Sb(28) and Cs(8)Cd(18)Sb(28), were synthesized and reinvestigated. These clathrates exhibit unique and extensive superstructural ordering of the clathrate-I structure that was not initially reported. Cs(8)Cd(18)Sb(28) orders in the Ia3̄d space group (no. 230...

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Bibliografische gegevens
Gepubliceerd in:Chem Sci
Hoofdauteurs: Owens-Baird, Bryan, Yox, Philip, Lee, Shannon, Carroll, Xian B., Grass Wang, Suyin, Chen, Yu-Sheng, Lebedev, Oleg I., Kovnir, Kirill
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: The Royal Society of Chemistry 2020
Onderwerpen:
Chemistry
Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC8162314/
https://ncbi.nlm.nih.gov/pubmed/34094291
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc03846f
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