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Chemically driven superstructural ordering leading to giant unit cells in unconventional clathrates Cs(8)Zn(18)Sb(28) and Cs(8)Cd(18)Sb(28)
The unconventional clathrates, Cs(8)Zn(18)Sb(28) and Cs(8)Cd(18)Sb(28), were synthesized and reinvestigated. These clathrates exhibit unique and extensive superstructural ordering of the clathrate-I structure that was not initially reported. Cs(8)Cd(18)Sb(28) orders in the Ia3̄d space group (no. 230...
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| Publicado no: | Chem Sci |
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| Main Authors: | , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
The Royal Society of Chemistry
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8162314/ https://ncbi.nlm.nih.gov/pubmed/34094291 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc03846f |
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