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Controlling superstructural ordering in the clathrate-I Ba(8)M(16)P(30) (M = Cu, Zn) through the formation of metal–metal bonds
Order–disorder–order phase transitions in the clathrate-I Ba(8)Cu(16)P(30) were induced and controlled by aliovalent substitutions of Zn into the framework. Unaltered Ba(8)Cu(16)P(30) crystallizes in an ordered orthorhombic (Pbcn) clathrate-I superstructure that maintains complete segregation of met...
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| Publicado no: | Chem Sci |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5437377/ https://ncbi.nlm.nih.gov/pubmed/28580103 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc00354d |
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