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Reversible OH-bond activation and amphoterism by metal–ligand cooperativity of calix[4]pyrrolato aluminate

Most p-block metal amides irreversibly react with metal alkoxides when subjected to alcohols, making reversible transformations with OH-substrates a challenging task. Herein, we describe how the combination of a Lewis acidic square-planar-coordinated aluminum(iii) center with metal–ligand cooperativ...

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Publicat a:Chem Sci
Autors principals: Sigmund, Lukas M., Greb, Lutz
Format: Artigo
Idioma:Inglês
Publicat: The Royal Society of Chemistry 2020
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC8161688/
https://ncbi.nlm.nih.gov/pubmed/34094227
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc03602a
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