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Reversible homolytic activation of water via metal–ligand cooperativity in a T-shaped Ni(ii) complex
A T-shaped Ni(ii) complex [(Tol,Ph)DHPy]Ni has been prepared and characterized. EPR spectra and DFT calculations of this complex suggest that the electronic structure is best described as a high-spin Ni(ii) center antiferromagnetically coupled with a ligand-based radical. This complex reacts with wa...
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| Vydáno v: | Chem Sci |
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| Hlavní autoři: | , , , |
| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
Royal Society of Chemistry
2018
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| Témata: | |
| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6354739/ https://ncbi.nlm.nih.gov/pubmed/30809351 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc03719a |
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