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Generation and Oxidative Reactivity of a Ni(II) Superoxo Complex via Ligand-Based Redox Non-Innocence
Metal ligand cooperativity is a powerful strategy in transition metal chemistry. This type of mechanism for the activation of O(2) is best exemplified by heme centers in biological systems. While aerobic oxidations with Fe and Cu are well precedented, Ni-based oxidations are frequently less common d...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8048103/ https://ncbi.nlm.nih.gov/pubmed/32429663 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c03244 |
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