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Redox, transmetalation, and stacking properties of tetrathiafulvalene-2,3,6,7-tetrathiolate bridged tin, nickel, and palladium compounds

Here we report that capping the molecule TTFtt (TTFtt = tetrathiafulvalene-2,3,6,7-tetrathiolate) with dialkyl tin groups enables the isolation of a stable series of redox congeners and facile transmetalation to Ni and Pd. TTFtt has been proposed as an attractive building block for molecular materia...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Xie, Jiaze, Boyn, Jan-Niklas, Filatov, Alexander S., McNeece, Andrew J., Mazziotti, David A., Anderson, John S.
Formato: Artigo
Idioma:Inglês
Publicado em: The Royal Society of Chemistry 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8145528/
https://ncbi.nlm.nih.gov/pubmed/34084362
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc04381k
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