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Mechanism of copper-free Sonogashira reaction operates through palladium-palladium transmetallation

The seminal contributions by Sonogashira, Cassar and Heck in mid 1970s on Pd/Cu- and Pd-catalysed (copper-free) coupling of acetylenes with aryl or vinyl halides have evolved in myriad applications. Despite the enormous success both in academia and in industry, however, critical mechanistic question...

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Detalhes bibliográficos
Publicado no:Nat Commun
Main Authors: Gazvoda, Martin, Virant, Miha, Pinter, Balazs, Košmrlj, Janez
Formato: Artigo
Idioma:Inglês
Publicado em: Nature Publishing Group UK 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6240041/
https://ncbi.nlm.nih.gov/pubmed/30446654
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-018-07081-5
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