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Mechanism of copper-free Sonogashira reaction operates through palladium-palladium transmetallation
The seminal contributions by Sonogashira, Cassar and Heck in mid 1970s on Pd/Cu- and Pd-catalysed (copper-free) coupling of acetylenes with aryl or vinyl halides have evolved in myriad applications. Despite the enormous success both in academia and in industry, however, critical mechanistic question...
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| Veröffentlicht in: | Nat Commun |
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| Hauptverfasser: | , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
Nature Publishing Group UK
2018
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6240041/ https://ncbi.nlm.nih.gov/pubmed/30446654 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-018-07081-5 |
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