Pyridine Wingtip in [Pd(Py-tzNHC)(2)](2+) Complex Is a Proton Shuttle in the Catalytic Hydroamination of Alkynes

[Image: see text] The cationic palladium(II) complex 1 of pyridyl-mesoionic carbene ligand catalyzes Markovnikov-selective intermolecular hydroamination between anilines and terminal alkynes into the corresponding imines. The reaction proceeds at room temperature, in the absence of additives, with e...

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Bibliographic Details
Published in:Org Lett
Main Authors: Virant, Miha, Mihelač, Mateja, Gazvoda, Martin, Cotman, Andrej E., Frantar, Anja, Pinter, Balazs, Košmrlj, Janez
Format: Artigo
Language:Inglês
Published: American Chemical Society 2020
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC7308070/
https://ncbi.nlm.nih.gov/pubmed/31999464
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.0c00203
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