Loading...

A practical catalytic reductive amination of carboxylic acids

We report reductive alkylation reactions of amines using carboxylic acids as nominal electrophiles. The two-step reaction exploits the dual reactivity of phenylsilane and involves a silane-mediated amidation followed by a Zn(OAc)(2)-catalyzed amide reduction. The reaction is applicable to a wide ran...

Full description

Saved in:
Bibliographic Details
Published in:Chem Sci
Main Authors: Stoll, Emma L., Tongue, Thomas, Andrews, Keith G., Valette, Damien, Hirst, David J., Denton, Ross M.
Format: Artigo
Language:Inglês
Published: The Royal Society of Chemistry 2020
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC8161228/
https://ncbi.nlm.nih.gov/pubmed/34123174
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc02271c
Tags: Add Tag
No Tags, Be the first to tag this record!