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Investigation and improvement of catalytic activity of G-quadruplex/hemin DNAzymes using designed terminal G-tetrads with deoxyadenosine caps

It is generally acknowledged that G-quadruplexes (G4s) acquire peroxidase activity upon interaction with hemin. Hemin has been demonstrated to bind selectively to the 3′-terminal G-tetrad of parallel G4s via end-stacking; however, the relationships between different terminal G-tetrads and the cataly...

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Bibliographische Detailangaben
Veröffentlicht in:Chem Sci
Hauptverfasser: Cao, Yanwei, Ding, Pi, Yang, Luyan, Li, Wenjing, Luo, Yu, Wang, Jine, Pei, Renjun
Format: Artigo
Sprache:Inglês
Veröffentlicht: The Royal Society of Chemistry 2020
Schlagworte:
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC8159390/
https://ncbi.nlm.nih.gov/pubmed/34094131
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc01905d
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