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Enantioselective para-Claisen Rearrangement for the Synthesis of Illicium-Derived Prenylated Phenylpropanoids
[Image: see text] The development of the first enantioselective para-Claisen rearrangement has been achieved. Using a chiral aluminum Lewis acid, illicinole is rearranged to give (−)-illicinone A (er 87:13), which can then be converted into more complex Illicium-derived prenylated phenylpropanoids....
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| 出版年: | Org Lett |
|---|---|
| 主要な著者: | , , , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
American
Chemical Society
2021
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| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8155563/ https://ncbi.nlm.nih.gov/pubmed/33856817 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.1c00620 |
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