Nalaganje...

Aromatic Claisen Rearrangements of O-prenylated tyrosine and model prenyl aryl ethers: Computational study of the role of water on acceleration of Claisen rearrangements

LynF, an enzyme from the TruF family, O-prenylates tyrosines in proteins; subsequent Claisen rearrangements give C-prenylated tyrosine products. These reactions in tyrosines and model phenolic systems have been explored with DFT and SCS-MP2 calculations. Various ab initio benchmarks have been comput...

Popoln opis

Shranjeno v:
Bibliografske podrobnosti
Main Authors: Osuna, Sílvia, Kim, Seonah, Bollot, Guillaume, Houk, K. N.
Format: Artigo
Jezik:Inglês
Izdano: 2013
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC3873100/
https://ncbi.nlm.nih.gov/pubmed/24376368
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ejoc.201201738
Oznake: Označite
Brez oznak, prvi označite!