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Detection of Water Molecules on the Radical Transfer Pathway of Ribonucleotide Reductase by (17)O Electron–Nuclear Double Resonance Spectroscopy

[Image: see text] The role of water in biological proton-coupled electron transfer (PCET) is emerging as a key for understanding mechanistic details at atomic resolution. Here we demonstrate (17)O high-frequency electron–nuclear double resonance (ENDOR) in conjunction with H(2)(17)O-labeled protein...

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Foilsithe in:J Am Chem Soc
Main Authors: Hecker, Fabian, Stubbe, JoAnne, Bennati, Marina
Formáid: Artigo
Teanga:Inglês
Foilsithe: American Chemical Society 2021
Rochtain Ar Líne:https://ncbi.nlm.nih.gov/pmc/articles/PMC8154519/
https://ncbi.nlm.nih.gov/pubmed/33957040
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.1c01359
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