Rollover Cyclometalation vs Nitrogen Coordination in Tetrapyridyl Anticancer Gold(III) Complexes: Effect on Protein Interaction and Toxicity

[Image: see text] In this work, a pair of gold(III) complexes derived from the analogous tetrapyridyl ligands H(2)biqbpy1 and H(2)biqbpy2 was prepared: the rollover, bis-cyclometalated [Au(biqbpy1)Cl ([1]Cl) and its isomer [Au(biqbpy2)Cl ([2]Cl). In [1](+), two pyridyl rings coordinate to the metal...

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Détails bibliographiques
Publié dans:JACS Au
Auteurs principaux: Zhou, Xue-Quan, Carbo-Bague, Imma, Siegler, Maxime A., Hilgendorf, Jonathan, Basu, Uttara, Ott, Ingo, Liu, Rongfang, Zhang, Liyan, Ramu, Vadde, IJzerman, Adriaan P., Bonnet, Sylvestre
Format: Artigo
Langue:Inglês
Publié: American Chemical Society 2021
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC8154207/
https://ncbi.nlm.nih.gov/pubmed/34056633
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacsau.0c00104
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