Photochemical Resolution of a Thermally Inert Cyclometalated Ru(phbpy)(N–N)(Sulfoxide)(+) Complex

[Image: see text] In this work a photosubstitution strategy is presented that can be used for the isolation of chiral organometallic complexes. A series of five cyclometalated complexes Ru(phbpy)(N−N)(DMSO-κS)](PF(6)) ([1]PF(6)-[5]PF(6)) were synthesized and characterized, where Hphbpy = 6′-phenyl-2...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Lameijer, Lucien N., van de Griend, Corjan, Hopkins, Samantha L., Volbeda, Anne-Geert, Askes, Sven H. C., Siegler, Maxime A., Bonnet, Sylvestre
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2018
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6331141/
https://ncbi.nlm.nih.gov/pubmed/30525567
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b10264
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