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Synthesis of secondary and tertiary amides without coupling agents from amines and potassium acyltrifluoroborates (KATs)

Although highly effective for most amide syntheses, the activation of carboxylic acids requires the use of problematic coupling reagents and is often poorly suited for challenging cases such as N-methyl amino acids. As an alternative to both secondary and tertiary amides, we report their convenient...

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書目詳細資料
發表在:Chem Sci
Main Authors: Schuhmacher, Anne, Shiro, Tomoya, Ryan, Sarah J., Bode, Jeffrey W.
格式: Artigo
語言:Inglês
出版: The Royal Society of Chemistry 2020
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在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC8152719/
https://ncbi.nlm.nih.gov/pubmed/34094137
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc01330g
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