Transition-metal-free C(sp(3))–H/C(sp(3))–H dehydrogenative coupling of saturated heterocycles with N-benzyl imines

A unique C(sp(3))–H/C(sp(3))–H dehydrocoupling of N-benzylimines with saturated heterocycles is described. Using super electron donor (SED) 2-azaallyl anions and aryl iodides as electron acceptors, single-electron-transfer (SET) generates an aryl radical. Hydrogen atom transfer (HAT) from saturated...

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Bibliografiske detaljer
Udgivet i:Chem Sci
Main Authors: Liu, Zhengfen, Li, Minyan, Deng, Guogang, Wei, Wanshi, Feng, Ping, Zi, Quanxing, Li, Tiantian, Zhang, Hongbin, Yang, Xiaodong, Walsh, Patrick J.
Format: Artigo
Sprog:Inglês
Udgivet: The Royal Society of Chemistry 2020
Fag:
Chemistry
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC8152681/
https://ncbi.nlm.nih.gov/pubmed/34094139
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc00031k
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